CAROLINA BIOLOGICAL SUPPLY CO -- 85-2860,CARBON DISULFIDE -- -
===================== Product Identification ===================== Product ID:85-2860,CARBON DISULFIDE MSDS Date:02/02/1998 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD City:BURLINGTON State:NC ZIP:27215-3387 Country:US Info Phone Num:800-227-1150 Emergency Phone Num:(800)424-9300 Preparer's Name:NOT PROVIDED. Chemtrec Ind/Phone:(800)424-9300 CAGE:59896 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-98-A-0118-0134 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DISULFIDE CAS:75-15-0 RTECS #:FF6650000 = Wt:100. Other REC Limits:NOT PROVIDED. OSHA PEL:20 PPM Code:F ACGIH TLV:31 MG/M3;10 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXTREMELY FLAMMABLE. POISON. TOXIC BY ORAL INTAKE, INHALATION OR PROLONGED CONTACT WITH SKIN. ACUTE EXPOSURE CAN RESULT IN NARCOSIS AND ANESTHESIA FOLLOWED BY RESPIRATORY FAILURE. SEVERE IRRITATION OR BURNS TO SKIN AND EYES. EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. CHRONIC: PSYCH OLOGICAL DISTURBANCES, IRRITATION OF RESPIRATORY SYSTEM, BLURRED VISION, ANEMIA, DAMAGE TO CENTRAL NERVOUS SYSTEM, CARDIOVASCULAR SYSTEM, LIVER, KIDNEY AND EYES. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION OR BURNS TO SKIN AND EYES. EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY T RACT. Medical Cond Aggravated by Exposure:NONE LISTED. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, RAISING AND LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL PHYSICIAN OR POISON CONTROL CENTER IMMED IATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=-30.C, -22.F Autoignition Temp:=100.C, 212.F Lower Limits:1.3 Upper Limits:50.0 Extinguishing Media:DRY CHEMICAL (ABC); CARBON DIOXIDE (CO2); WATER FOG OR WATER SPRAY. IT IS BEST EXTINGUISHED BY THE USE OF WATER FOG OR SPRAY. Fire Fighting Procedures:COMPLETELY BLANKET THE FIRE WITH WATER FOG OR WATER SPRAY TO PUT OUT THE FIRE AND COOL THE EQUIPMENT. THIS WILL PREVENT RE-IGNITION OF CARBON DISULFIDE. CARBON DIOXIDE AND DRY CHEMICAL MAY BE USED ON SMALL FIRES. FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard:CARBON DISULFIDE IS HIGHLY FLAMMABLE, VOLATILE LIQUID WITH LOW FLASH POINT, WIDE EXPLOSIVE RANGE AND AN EXTREMELY LOW AUTOIGNITION TEMPERATURE. CONTACT OF VAPOR IN CONCENTRATION WITHIN EXPLOSIVE RANGE WITH MATERIALS HAVING TEMPERATURES OF 212F/MORE MAY CAUSE AUTOIGNITION. THIS MATERIAL IS SENSITIVE TO STATIC DISCHARGE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB MATERIAL WITH ABSORBANT AND CONTAINERIZE FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM FLAMMABLE MATERIALS AND SOURCES OF COMBUSTION. FIREFIGHTING EQUIPMENT SHOULD BE WITHIN EASY REACH. HIGHLY VOLATILE. DO NOT STORE IN DIRECT SUNLIGHT . Other Precautions:DO NOT BREATHE VAPORS. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. REMOVE AND WASH CONTAMINATED CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:LOCAL/MECHANICAL:YES Protective Gloves:NITRILE, BUTYL OR EQUIVALENT Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT ALL TIMES. Other Protective Equipment:LAB COAT, EYE WASH AND SAFETY SHOWER. Work Hygienic Practices:NOT PROVIDED. Supplemental Safety and Health PRODUCT CODE: 85-2860; 85-2880 ================== Physical/Chemical Properties ================== HCC:F5 NRC/State Lic Num:NOT RELEVANT. Boiling Pt:=46.1C, 115.F Melt/Freeze Pt:=-111.5C, -169.F Vapor Pres:400MM@20C Vapor Density:2.64 Spec Gravity:1.2629 pH:NOT APPLICAPLE. Viscosity:NOT PROVIDED. Evaporation Rate & Reference:22.6(BUAC=1) Solubility in Water:0.210 GRAMS Appearance and Odor:CLEAR, COLORLESS TO FAINT, YELLOW LIQUID; STRONG DISAGREEABLE ODOR. Percent Volatiles by Volume:100 Corrosion Rate:NOT PROVIDED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, AZIDES, ZINC, ALUMINUM, SODIUM, POTASSIUM, AMINES, MOST COMMON METALS, CHLORINE, FLUORINE, HYPOCHLORITE. Stability Condition to Avoid:HEAT, FLAME, SOURCES OF IGNITION, SHOCK, FRICTION, AIR, SUNLIGHT Hazardous Decomposition Products:IN AIR, THIS PRODUCT HAS AN AUTOIGNITION POINT OF 212F AND BURNS TO FORM CARBON DIOXIDE AND CARBON MONOXIDE. HMIS: & SULFUR OXIDES. =================== Toxicological Information =================== Toxicological Information:NO INFORMATION IS AVAILABLE. ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBERS: P022. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:CARBON DISULFIDE, 3, UN1131, I ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III, SECTIONS 311/312 HAZARD CATEGORIES: ACUTE, CHRONIC. SARA SECTION 313: PRODUCT OR COMPONENTS: CARBON DISULFIDE, SARA EHS SEC. 302 TPQ: YES, CERCLA SEC. 103, RQ LBS.: 100, RCRA: YES. Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. State Regulatory Information:NOT PROVIDED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.